<doi_batch xmlns="http://www.crossref.org/schema/4.4.0" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" version="4.4.0"><head><doi_batch_id>f087edd4-ff5f-499f-bf89-de93705ff814</doi_batch_id><timestamp>20251118091114481</timestamp><depositor><depositor_name>wseas:wseas</depositor_name><email_address>mdt@crossref.org</email_address></depositor><registrant>MDT Deposit</registrant></head><body><journal><journal_metadata language="en"><full_title>International Journal of Applied Sciences &amp; Development</full_title><issn media_type="electronic">2945-0454</issn><archive_locations><archive name="Portico" /></archive_locations><doi_data><doi>10.37394/232029</doi><resource>https://wseas.com/journals/asd/</resource></doi_data></journal_metadata><journal_issue><publication_date media_type="online"><month>1</month><day>29</day><year>2025</year></publication_date><publication_date media_type="print"><month>1</month><day>29</day><year>2025</year></publication_date><journal_volume><volume>4</volume><doi_data><doi>10.37394/232029.2025.4</doi><resource>https://wseas.com/journals/asd/2025.php</resource></doi_data></journal_volume></journal_issue><journal_article language="en"><titles><title>Effect of Precursor Concentration on Optical, Grain Sizes and Structural Properties of Green Synthesized Zinc Oxide Nanoparticles</title></titles><contributors><person_name sequence="first" contributor_role="author"><given_name>Samaila</given_name><surname>H.</surname><affiliation>Department of Physics, Faculty of Physical Sciences, University of Maiduguri, P.M.B. 1069, Maiduguri, Borno, NIGERIA</affiliation></person_name><person_name sequence="additional" contributor_role="author"><given_name>Yerima</given_name><surname>J. B.</surname><affiliation>Department of Physics, Faculty of Physical Sciences, Modibbo Adama University, P.M.B. 2076, Yola, Adamawa, NIGERIA</affiliation></person_name><person_name sequence="additional" contributor_role="author"><given_name>Balami</given_name><surname>D. S.</surname><affiliation>Department of Physics, Faculty of Physical Sciences, University of Maiduguri, P.M.B. 1069, Maiduguri, Borno, NIGERIA</affiliation></person_name></contributors><jats:abstract xmlns:jats="http://www.ncbi.nlm.nih.gov/JATS1"><jats:p>Researchers are increasingly interested in zinc oxide (ZnO) nanoparticles for optoelectronic applications because of their wide band gap (~3.37 eV), large exciton binding energy (~60 meV) at room temperature, non-toxicity, environmental friendliness, and transparency over the visible light spectrum. In this study, ZnO nanoparticles were synthesized using a green method: zinc acetate served as the precursor, and Jatropha leaf extract as both reducing and capping agent; the reaction was carried out in Chemistry Advanced Research Laboratory SHESTCO using distilled water while the pH of the reaction was adjusted to 11.6 via dropwise addition of 1 M sodium hydroxide. The resulting nanoparticles were characterized using UV-Vis spectroscopy, X-ray diffraction (XRD), scanning electron microscopy (SEM), and energy-dispersive X-ray spectrometry (EDX). UV-Vis spectra showed absorption peaks between 372 and 400 nm, corresponding to band gaps of about 3.11 to 3.34 eV. XRD data estimated the average nanoparticle size of three nanoparticles to be in the range of ~16.62 to ~21.11 nm. EDX revealed that the nanoparticles contained approximately 78.32% zinc and 12.78% oxygen by composition signals, while SEM images showed that the particles are agglomerated in morphology.</jats:p></jats:abstract><publication_date media_type="online"><month>11</month><day>18</day><year>2025</year></publication_date><publication_date media_type="print"><month>11</month><day>18</day><year>2025</year></publication_date><pages><first_page>244</first_page><last_page>253</last_page></pages><publisher_item><item_number item_number_type="article_number">26</item_number></publisher_item><ai:program xmlns:ai="http://www.crossref.org/AccessIndicators.xsd" name="AccessIndicators"><ai:free_to_read start_date="2025-11-18" /><ai:license_ref applies_to="am" start_date="2025-11-18">https://wseas.com/journals/asd/2025/a52asd-020(2025).pdf</ai:license_ref></ai:program><archive_locations><archive name="Portico" /></archive_locations><doi_data><doi>10.37394/232029.2025.4.26</doi><resource>https://wseas.com/journals/asd/2025/a52asd-020(2025).pdf</resource></doi_data><citation_list><citation key="ref0"><doi>10.46488/nept.2020.v19i05.002</doi><unstructured_citation>Gnanasangeetha, D., &amp; Suresh, M. (2020). A review on green synthesis of metal and metaloxide nanoparticles. Nature Environment and Pollution Technology, 19(5), 1789-1800. </unstructured_citation></citation><citation key="ref1"><doi>10.1155/2020/7459042</doi><unstructured_citation>Demissie, M. G., Sabir, F. K., Edossa, G. D. and Gonfa, B. A. (2020) Synthesis of Zinc Oxide Nanoparticles Using Leaf Extract of Lippia adoensis and Evaluation of Its Antibacterial Activity, Hindawi Journal of Chemistry2020, https://doi.org/10.1155/2020/7459042 </unstructured_citation></citation><citation key="ref2"><doi>10.1177/15589250211046242</doi><unstructured_citation>Xu, J. H. (2021). A review of the green synthesis o fZnO nanoparticles using plant extracts and their prospects for application in antibacterial textiles. Journal of Engineered Fibers and Fabrics,16 1– 14https://doi.org/10.1177/15589250211046242 . </unstructured_citation></citation><citation key="ref3"><doi>10.1016/j.cej.2020.124965</doi><unstructured_citation>Yap, P. L., Auyoong, Y. L., Hassan, K., Farivar, F., Tran, D. N., Ma, J., &amp; Losic, D. (2020). Multithiol functionalized graphene biosponge via photoinitiated thiol-ene click chemistry for efficient heavy metal ions adsorption. Chemical Engineering Journal, 395, 124965. </unstructured_citation></citation><citation key="ref4"><unstructured_citation>Hajiashrafi, S. and Motakef-Kazemi, N. (2018) Green synthesis of zinc oxide nanoparticles using parsley extract. Nanomed Researc Journal 3(1): 44-50. DOI: 10.22034/nmrj.2018.01.007 </unstructured_citation></citation><citation key="ref5"><doi>10.12988/ces.2018.8228</doi><unstructured_citation>Sierra, M. J., Herrera, A. P., &amp; Ojeda, K. A. (2018). Synthesis of zinc oxide nanoparticles from mango and soursop leaf extracts. Contemporary Engineering Sciences, 11(8), 395- 403 </unstructured_citation></citation><citation key="ref6"><unstructured_citation>Dönmez, S. (2020,)Green Synthesis of Zinc Oxide Nanoparticles Using Zingiber Officinale Root Extract and Their Applications in Glucose Biosensor, El-Cezerî Journal of Science and Engineering, 7 (3); 1191-1200. </unstructured_citation></citation><citation key="ref7"><doi>10.1088/1757-899x/805/1/012003</doi><unstructured_citation>Balogun, S. W., Sanusi, Y. K. and Agboluaje, B. A. (2020), Green Synthesis, characterization of Zinc oxide nanoparticles using Chromolaena odorata extract and evaluation of its properties for photoanode of solar cells, Nanotechnology Applications in Africa: Opportunities and Constraints IOP Conf. Series: Materials Science and Engineering 805 doi:10.1088/1757899X/805/1/012003 </unstructured_citation></citation><citation key="ref8"><doi>10.1016/j.eti.2019.100526</doi><unstructured_citation>Ossai, I. C., Ahmed, A., Hassan, A., &amp; Hamid, F. S. (2020). Remediation of soil and water contaminated with petroleum hydrocarbon: A review. Environmental Technology &amp; Innovation, 17, 100526. </unstructured_citation></citation><citation key="ref9"><unstructured_citation>Bandeira1, M. G.-E. (2018). Green synthesis of zinc oxide nanoparticles: a review of the synthesis methodology and mechanism of formation. 1 - 32. </unstructured_citation></citation><citation key="ref10"><doi>10.9790/5736-1002016064</doi><unstructured_citation>Wafula, B. J. Masika E. and Onindo, C. (2020), ZnO Nanoparticles (ZnO-NPs): Synthesis Using Tithonia diversifolia, Characterization and in-vitroAntimicrobial Bioassays." IOSR Journal of Applied Chemistry (IOSR-JAC), 13(8), 14-21. https://DOI.10.9790/5736-1308011421 </unstructured_citation></citation><citation key="ref11"><unstructured_citation>Noorjahan, C. M., Shahina, S. K. J., Deepika, T. and Rafiq, S. (2015) Green Synthesis and Characterization of Zinc Oxide Nanoparticles from Neem (Azadirachta indicia), International Journal of Scientific Engineering and Technology Research 4(30), 5751-5753 </unstructured_citation></citation><citation key="ref12"><unstructured_citation>Taherian, S. M. R., Hosseini, A. H., Jafari, A. and Etminan, A. (2018) The Green Synthesis and Characterization of Zinc Oxide Nanoparticles from the Leaf Extracts of Satureja hortensis. Herb. Med. J.; 3(4)147-53 DOI: 10.22087/herb%20med%20j.v3i4.696 </unstructured_citation></citation><citation key="ref13"><unstructured_citation>Vaishnav, J. Subha, V. Kirubanandan, S. Arulmozhi, M. and Renganathan S. (2017), green synthesis of zinc oxide nanoparticles by celosia Argentea and its characterization, Journal of Optoelectronics and Biomedical Materials 9(1) 59 – 71 </unstructured_citation></citation><citation key="ref14"><doi>10.12688/f1000research.73272.2</doi><unstructured_citation>Kaningini GA, Azizi S, Nyoni H., Fhatuwani Nixwel Mudau , Keletso Cecilia Mohale, Malik Maaza (2022). Green. synthesis and characterization of zinc oxide nanoparticles usingbush tea (Athrixia phylicoidesDC) natural extract: assessment of the synthesis process, F1000Research 2022, 10:1077 Last updated: 27 JAN 2022 https://doi.org/10. 12688/f1000research.73272.2 </unstructured_citation></citation><citation key="ref15"><doi>10.1166/jnn.2010.2334</doi><unstructured_citation>Jeong, Ek; Yu, H; Kim, Y; Yi, G; Choi, Y; and Han, S (2010), Local Structural and Optical Properties of ZnO Nanoparticles, Journal of Nanoscience and Nanotech -nology, 10 ( 5). 3562-3565(4) DOI: https://doi.org/10.1166/jnn. 2010.2334 </unstructured_citation></citation><citation key="ref16"><unstructured_citation>Wolgamott, J. C. (2017). Analysis of Zinc Oxide Thin Films Synthesized By Sol-Gel via Spin Coating (Doctoral dissertation, The University of Wisconsin-Milwaukee). </unstructured_citation></citation><citation key="ref17"><doi>10.5402/2012/372505</doi><unstructured_citation>Talam, S., Karumuri, S. R. &amp; Gunnam, N. (2012). Synthesis, Characterization, and Spectroscopic Properties ofZnO Nanoparticles, International Scholarly Research NetworkISRN Nanotechnology 372505, 1 - 6 doi:10.5402/2012/372505 </unstructured_citation></citation><citation key="ref18"><unstructured_citation>Alwan, R. M., Kadhim, Q. A., Sahan, K. M., Ali, R. A., Mahdi, R. J., Kassim, N. A., &amp; Jassim, A. N. (2015). Synthesis of zinc oxide nanoparticles via sol–gel route and their characterization. Nanoscience and Nanotechnology, 5(1), 1-6. </unstructured_citation></citation><citation key="ref19"><doi>10.4491/eer.2020.454</doi><unstructured_citation>Shamshad, S. Rashid, J. Ihsan-ul-haq, N. I., and Awan, S. U. (2021). Synthesis of zinc oxide and silver nanoparticles using ficus palmataForssk leaf extracts and assessment of antibacterial activity, Environ. Eng. Res. 2021; 26(6) 1226- 1025https://doi.org/10.4491/eer.2020.454 </unstructured_citation></citation><citation key="ref20"><unstructured_citation>Makori, N. E., Oeba1, D. A. and Mosiori, C. O. (2017), Relationship between Band gap and particle size of Cadmium sulfide Quantum Dots, Chemistry Research Journal, 2(5):15-21 </unstructured_citation></citation><citation key="ref21"><doi>10.5402/2012/372505</doi><unstructured_citation>Talam, S., Karumuri, S. R. &amp; Gunnam, N. (2012). Synthesis, Characterization, and Spectroscopic Properties ofZnO Nanoparticles, International Scholarly Research NetworkISRN Nanotechnology 372505, 1 - 6 doi:10.5402/2012/372505 </unstructured_citation></citation><citation key="ref22"><unstructured_citation>Zak, A. K., Abdul-Majid, W. H.; Abrishami, M. E. &amp; Yousefi, R. (2011). Solid State Sciences 13, 251 </unstructured_citation></citation><citation key="ref23"><doi>10.1016/j.physe.2013.12.009</doi><unstructured_citation>Sahai, A. &amp; Goswami, N. (2013). Structural and Vibrational Properties of ZnO Nanoparticles Synthesized by Chemical Precipitation Method, Physica E, http://dx.doi.org/10.1016 /j. physe.2013.12.009 </unstructured_citation></citation><citation key="ref24"><unstructured_citation>Yadav,R. K. &amp; Chauhan, P. (2019), Estimation of lattice strain in Mn-doped ZnO nanoparticles and its effect on structural and optical properties, Indian Journal of Pure &amp; Applied Physics 57. 881-890</unstructured_citation></citation></citation_list></journal_article></journal></body></doi_batch>